Pesticide Selection for Water Quality Protection
A. H. Bruneau, Extension Crop Science Specialist
R. J. Cooper, Turfgrass Research and Teaching
L. T. Lucas, Extension Plant Pathology Specialist
(Note:
The following information is a supplement to the Water Quality Water Management
series and replaces the Pesticide Leaching Potential Rating Tables found in
publications WQWM-154, 155 and 156.)
While
research has shown that pollution of surface and groundwater supplies from
turfgrass pesticide application is uncommon, the turf manager should still
strive to avoid potential environmental contamination when choosing a
pesticide. Unfortunately, there is little information available to aid in
choosing a chemical control based upon minimizing potential leaching. Although
several computer models exist to evaluate leaching potential, they are
difficult to use and require extensive training. In an effort to provide a
relatively simple method for identifying pesticides with the least potential
for contaminating groundwater, R.L. Warren and J. B. Weber of N C State
University have developed a pesticide ranking system known as the Pesticide
Leaching Potential (PLP) Index. The index uses several pesticide
characteristics to estimate potential leaching to groundwater. These
characteristics include the ability to bind to soil organic matter, time
required for the pesticide to degrade (persistence), rate of application, and
the amount of an application that actually penetrates the turf canopy and
reaches the soil.
The PLP
index for various turfgrass pesticides labeled for use in North Carolina can be
found on the reverse side. The index is based on a scale of 0 - 100 with a
higher number indicating an increased likelihood for leaching. For example, a
rating of 5 would indicate that a material had a very low potential for
leaching while a pesticide with a PLP index of 95 would have a very high
probability for leaching and should be avoided, especially in environmentally
sensitive areas.
It is
important to note that the PLP index is determined primarily based on
characteristics of the pesticide and that other factors in the turfgrass
ecosystem also influence leaching potential. Potential leaching into
groundwater is also affected by soil pH, soil type, photo decomposition
(degradation by sunlight), microbial decomposition, volatilization (pesticide
evaporation), and other factors.
To minimize
leaching potential, it is generally best to choose pesticides which have a low
PLP index when possible. If two possible pesticide choices have a similar PLP
index (within 5 points of each other) their leaching potential is fairly
similar. As a rough guideline, materials having a PLP index less than 40 would
have a low leaching potential while a PLP index greater than 70 would indicate
that potential leaching was a concern. Also, pesticides are more likely to
leach in soils which are sandy, low in organic matter, and which have a pH of 6.0
or greater.
You should
also keep in mind that leaching is only one of many considerations in selecting
a pesticide. There will be some instances where a pesticide exhibits low
leaching potential but because of its high potential toxicity to wildlife, such
as fish, extra precautions may be necessary around water. These precautions
should be mentioned on the label.
Choosing
pesticides with low leaching potential is only one of many techniques available
to turfgrass managers to help protect water quality. Contact your local
Cooperative Extension Office for free publications regarding water quality
protection.
Pesticide Leaching Potential Index
|
Table 1. Herbicides
|
|
Common Name
|
Trade Name
|
Rate *
|
Index **
|
|
Fenoxaprop
|
Acclaim
|
0.18
|
0
|
|
Prodiamine
|
Barricade
|
0.75
|
1
|
|
Diclofop
|
Illoxan
|
1.50
|
10
|
|
Pendimethalin
|
Pre-M
|
3.00
|
18
|
|
Dithiopyr
|
Dimension
|
0.50
|
20
|
|
Metolachlor
|
Pennant
|
4.00
|
22
|
|
Sethoxydim
|
Vantage
|
0.28
|
26
|
|
MSMA
|
MSMA
|
3.00
|
27
|
|
Trifluralin
|
Treflan
|
3.00
|
32
|
|
Pronamide
|
Kerb
|
1.50
|
34
|
|
Glyphosate
|
Roundup
|
4.00
|
36
|
|
Oxadiazon
|
Ronstar
|
3.00
|
36
|
|
Benefin
|
Balan
|
3.00
|
36
|
|
Bentazon
|
Basagran
|
2.00
|
36
|
|
DCPA
|
Dacthal
|
10.50
|
38
|
|
Ethofumasate
|
Prograss
|
1.00
|
41
|
|
2,4-D
|
2,4-D
|
0.75
|
41
|
|
DSMA
|
Methar
|
5.00
|
41
|
|
Metsulfuron
|
DMC
|
0.10
|
42
|
|
Isoxaben
|
Gallery
|
1.00
|
44
|
|
Bensulide
|
Betasan
|
10.00
|
44
|
|
Oryzalin
|
Surflan
|
3.00
|
44
|
|
Napropamide
|
Devrinol
|
3.00
|
46
|
|
Asulam
|
Asulox
|
2.00
|
47
|
|
Metribuzin
|
Sencor
|
0.50
|
48
|
|
Atrazine
|
Aatrex
|
2.00
|
52
|
|
Triclopyr
|
Turflon
|
2.00
|
53
|
|
Simazine
|
Princep
|
2.00
|
54
|
|
Dicamba
|
Banvel
|
0.50
|
54
|
|
Imazaquin
|
Image
|
0.50
|
58
|
|
Mecoprop
|
MCPP
|
1.75
|
61
|
|
Siduron
|
Tupersan
|
10.00
|
64
|
|
* Maximum recommended
application rate (lb A.I./Acre)
** Pesticide Leaching Potential Index (0-100) where 0 = very low leaching
potential and 100 = very high leaching potential.
|
|
Table 2. Fungicides
|
|
Common Name
|
Trade Name
|
Rate *
|
Index **
|
|
Vinclozolin
|
Curlan
|
2.70
|
20
|
|
Fosetyl-AI
|
Aliette
|
17.40
|
25
|
|
Thiophanate methyl
|
Clearys 3336
|
2.70
|
31
|
|
Anilazine
|
Dyrene
|
5.40
|
31
|
|
Iprodione
|
Chipco
|
2.50
|
33
|
|
Mancozeb
|
Fore
|
8.70
|
36
|
|
Triadimefon
|
Bayleton
|
1.30
|
43
|
|
Propiconazole
|
Banner
|
1.50
|
45
|
|
Chlorothalonil
|
Daconil
|
19.60
|
46
|
|
Metalaxyl
|
Subdue
|
1.36
|
50
|
|
Propamocarb
|
Banol
|
7.24
|
51
|
|
Fenarimol
|
Rubigan
|
2.00
|
51
|
|
Chloroneb
|
Terraneb
|
7.00
|
51
|
|
Benomyl
|
Tersan
|
2.70
|
55
|
|
Maneb
|
Manzate
|
13.00
|
56
|
|
Etridiazole
|
Koban
|
6.50
|
65
|
|
* Maximum recommended
application rate (lb A.I./Acre)
** Pesticide Leaching Potential Index (0-100) where 0 = very low leaching
potential and 100 = very high leaching potential.
|
|
Table 3. Insecticides
|
|
Common Name
|
Trade Name
|
Rate *
|
Index **
|
|
Cyfluthrin
|
Tempo
|
0.09
|
0
|
|
Permetrin
|
Astro
|
0.90
|
12
|
|
Fenoxycarb
|
Award
|
1.50
|
19
|
|
Chlorpyrifos
|
Dursban
|
1.00
|
19
|
|
Fenamiphos
|
Nemacur
|
10.00
|
36
|
|
Acephate
|
Orthene
|
3.00
|
36
|
|
Fonofos
|
Crusade
|
3.90
|
37
|
|
Bendiocarb
|
Turcam
|
4.10
|
38
|
|
Carbaryl
|
Sevin
|
2.10
|
39
|
|
Diazinon
|
Diazinon
|
4.30
|
41
|
|
Isofenphos
|
Oftanol
|
1.90
|
44
|
|
Isazofos
|
Triumph
|
2.00
|
44
|
|